; InChI=1S/C14H10/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13/h1-10H, CSID:970, http://www.chemspider.com/Chemical-Structure.970.html (accessed 14:45, Apr 18, 2023), Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agencys EPISuite, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the. Some documentation and label information may refer to the legacy brand. Struct. 6 0 obj Environ Pollut. Gas chromatographic-mass spectrometric studies of reactions of tricyclic aromatic hydrocarbons with hypochlorite in dilute aqueous solution, J. D3 B!w m lc!7C,_ 1|}6>,74$$dA o K ?i_y[bN#[+O:^1\J+n]kqy.suP8:e8[aKTFXiJUk:u9VQ. It has also been identified in seafood collected from contaminated waters and in smoked and charcoal-broiled foods. Liu L, Yin QM, Yan X, Hu C, Wang W, Wang RK, Luo X, Zhang XW. Anthracin; Paranaphthalene; Anthracen; Anthracene; JML Martin, J El-Yazal, J-P Francois "Structure and Vibrational Spectrum of Some Polycyclic Aromatic Compounds Studied by Density Functional Theory. [5] Dehydration of glycerol gives acrolein which condenses with the amine followed by a cyclization. Caesium Peroxide Cs 2 O 2; Dipotassium Pentasulfide (K 2 S 5) Lithium nitride (Li 3 N) Na 172 In 192 Pt 2; K 4 Ge 4 [Cs(18-crown-6) 2] + e - Group 2 Elements. The compound with a phenanthrene skeleton and nitrogens at the 4 and 5 positions is known as phenanthroline. Disclaimer. Recommended Storage : Ambient temperatures, phenanthren, phenanthrin, phenanthracene, ravatite, phenantrin, phenanthren german, phenanthrene, pure, unii-448j8e5bst, ccris 1233, chembl46730, Electrophoresis, Western Blotting and ELISA, Chromatography and Mass Spectrometry Reagents, Laboratory Syringe Needles and Accessories, Lab Coats, Aprons, and Other Safety Apparel, Sharps Disposal Containers and Accessories, Classroom Laboratory Supplies and Consumables, Applied Biosystems TaqMan Assay and Arrays Search Tool, Applied Biosystems TaqMan Custom Assay Design Tools, Applied Biosystems Custom qPCR Primers and TaqMan Probes Tool, Chemical Storage and Management Resource Center. Uses advised against Food, drug, pesticide or biocidal product use. {|'9G Pyrene is a polycyclic aromatic hydrocarbon (PAH) consisting of four fused benzene rings, resulting in a flat aromatic system. 2014-09-30T09:58:39.238reyarbro /Parent 3 0 R Chromatogr., 18(3), 2000, 241-246. ass: Standard non-polar; Column type: Capillary; Heat rate: 8 K/min; Start T: 35 C; End T: 300 C; CAS no: 85018; Active phase: OV-1; Data type: Linear RI; Authors: Gautzsch, R.; Zinn, P., Use of incremental models to estimate the retention indexes of aromatic compounds, Chromatographia, 43(3/4), 1996, 163-176. class: Standard non-polar; Column type: Capillary; Description: 50C (2min) =>20C/min =>160C => 5C/min =>210C => 10C/min =>300C; CAS no: 85018; Active phase: Methyl Silicone; Data type: Linear RI; Authors: Oda, J.; Ichikawa, S.; Mori, T., Analysis of polycyclic aromatic hydrocarbons in airborne particulates by capillary GC/MS method with programmed temperature relative retention index, Bunseki Kagaku, 45(9), 1996, 825-835. class: Standard non-polar; Column length: 3.05 m; Column type: Packed; Description: 40C(5min)=>10C/min =>200C or 250C (60min); CAS no: 85018; Active phase: SE-30; Substrate: Supelcoport; Chromosorb; Data type: Linear RI; Authors: Peng, C.T. Chromatogr., 66, 1972, 43-53. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 50 C; End T: 280 C; CAS no: 85018; Active phase: HP-5 MS; Carrier gas: Helium; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Zhao, C.; Zeng, Y.; Wan, M.; Li, R.; Liang, Y.; Li, C.; Zeng, Z.; Chau, F.-T., Comparative analysis of essential oils from eight herbal medicines with pungent flavor and cool nature by GC-MS and chemometric resolution methods, J. Sep. 4.51922: 2428.448-70.96: Osborn and Douslin, 1975, 2: Coefficents calculated by NIST from author's data. The phenanthrene is a leaf-like crystal with a relative density of 1.179 (25/4 ) and a refractive index of 1.6450, melting point of 101 C and boiling point of 340 C. Although phenanthrenes are considered to constitute a relatively small group of natural products, discovering new phenanthrene derivatives and evaluating their prospective biological activities have become of great interest to many research groups worldwide. They are mainly synthesized . Jmol.jmolLink(jmolApplet0,"Frame Next","Next \u23ED");Jmol.jmolHtml(' ');Jmol.jmolLink(jmolApplet0,"Frame Prev","Prev \u23EE"); ; Kaiser-Farrell, C.; McCalla, D.R. ; Vassilaros, D.L. [2]. Chim., 45(4), 2000, 313-318. ass: Semi-standard non-polar; Column type: Capillary; Heat rate: 5 K/min; Start T: 80 C; End T: 275 C; CAS no: 85018; Active phase: C103H208; Carrier gas: H2; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Dumitrescu, V.; Buda, W.; Medvedovici, A., Evaluation of new stationary phases for capillary gas chromatography, Rev. Chemical Constituents from the Aerial Parts of Cyrtopodium paniculatum. A, 1096, 2005, 76-85. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 80 C; End T: 290 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zhao, C.-X. Oxford: 2010. Bond descriptions Examples: C-C single bond, C=C, double bond, C#C triple bond, C:C aromatic bond InChI=1S/C12H8N2/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1/h1-8H, InChI=1/C12H8N2/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1/h1-8H, monohydrate: C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.O, Except where otherwise noted, data are given for materials in their, As an indicator for alkyllithium reagents. Melting Point (C) Physical Form. ; Vilegas, W., Identification of polycyclic aromatic hydrocarbons in sugar cane soot by gas chromatography-mass spectrometry, Chromatographia, 46(11/12), 1997, 655-663. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 25 m; Column type: Capillary; Heat rate: 8 K/min; Start T: 50 C; End T: 250 C; End time: 12 min; Start time: 2 min; CAS no: 85018; Active phase: SE-54; Carrier gas: He; Data type: Normal alkane RI; Authors: Harland, B.J. SAFETY DATA SHEET Creation Date 01-May-2012 Revision Date 24-Dec-2021 Revision Number 5 1. certified reference material (2) . %PDF-1.4 A, 1096, 2005, 76-85. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 80 C; End T: 290 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zhao, C.-X. "Application of chelate Compounds in Analytical Chemistry", "Ni(I)Alkyl Complexes Bearing Phenanthroline Ligands: Experimental Evidence for CO2 Insertion at Ni(I) Centers", "Nickel-Catalyzed C-Alkylation of Nitroalkanes with Unactivated Alkyl Iodides", https://en.wikipedia.org/w/index.php?title=1,10-Phenanthroline&oldid=1142107804, Chemical articles with multiple compound IDs, Chemical articles with multiple CAS registry numbers, Chemical articles with multiple PubChem CIDs, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Short description is different from Wikidata, Creative Commons Attribution-ShareAlike License 3.0, mild neurotoxin, strong nephrotoxin, and powerful diuretic, This page was last edited on 28 February 2023, at 15:07. ; Balavoine, G.; Kagan, H.; Martin, R.H.; Deblecker, M., Chromatographie en phase vapeur d'helicenes et de diaryl-1,2-ethylenes, J. XXXIV. Soc. Chromatogr., 220, 1981, 195-252. umn class: Standard non-polar; Column length: 4 m; Column type: Packed; Start T: 170 C; CAS no: 85018; Active phase: OV-1; Carrier gas: Nitrogen; Substrate: Gas-Chrom Q (60-80 mesh); Data type: Normal alkane RI; Authors: Nicoud, J.F. A classic and well established explanation is based on Clar's rule. [13] Campo, L., et al. /Resources 2 0 R Got a better number? Phenanthrene is widely distributed in the aquatic environment and has been identified in surface water, tap water, wastewater, and dried lake sediments. ;PMr~M=7}b_VB{G.}p4I#M9{ B &B{h~ s__'mox?{S)+foXu?{L9J_?{#?oNO5gCoDn|~? Stable. [6], Several homoleptic complexes are known of the type [M(phen)3]2+. /Type/Page Cholet J, Decombat C, Delort L, Gainche M, Berry A, Ogeron C, Ripoche I, Vareille-Delarbre M, Vermerie M, Fraisse D, Felgines C, Rossary A, Ranouille E, Berthon JY, Tourrette A, Priam J, Saunier E, Troin Y, Senejoux F, Chalard P, Caldefie-Chzet F. Int J Mol Sci. ; Liang, Y.-Z. [/&gP;COw+ha1$j'aN7o;=idt}_ ] ^w|o~}muqU=cv(TE5Qu T9w?XsrMTBD ~0[]f=^Lp;f)\%q!e\m51c:%va?=) TU"}|m%aX~3$5 k(l7v&W'Vf`{uYbp>e2O_l`m$4~P#"H!w6rd?w?oRM/:^Y75wz.|#@7q& Y#N,1nV7(Q)dH}x~#yx!LFnHB85o. <> Auberon F, Olatunji OJ, Herbette G, Raminoson D, Antheaume C, Soengas B, Bont F, Lobstein A. Molecules. ; Barcock, R.A.; Lobanov, V.S. Epub 2008 Feb 19. 1,10-Phenanthroline (phen) is a heterocyclic organic compound. <> 148 A dihydronaphthalene 270 with a . Res. Chemosphere. This site needs JavaScript to work properly. 2016 Apr;149:130-6. Anthracene is a solid polycyclic aromatic hydrocarbon (PAH) of formula C 14 H 10, consisting of three fused benzene rings. '. Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals. Clipboard, Search History, and several other advanced features are temporarily unavailable. sur l'initiative du IX., , 1962, 132-140. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 40 C; End T: 280 C; End time: 10 min; CAS no: 85018; Active phase: DB-5; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Grung, M.; Lichtenthaler, R.; Ahel, M.; Tollefsen, K.-E.; Langford, K.; Thomas, K.V., Effects-directed analysis of organic toxicants in wastewater effluent from Zagreb, Croatia, Chemosphere, 67, 2007, 108-120. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 240 C; End time: 5 min; CAS no: 85018; Active phase: HP-5; Carrier gas: Helium; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Miyazawa, M.; Kawata, J., Identification of the Key Aroma Compounds in Dried Roots of Rubia cordifolia, L. Oleo Sci., 55(1), 2006, 37-39. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 60 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 30 C; End T: 260 C; End time: 28 min; Start time: 2 min; CAS no: 85018; Active phase: HP-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Leffingwell, J.C.; Alford, E.D., Volatile constituents of Perique tobacco, Electron. ; Yang, Z.C. A, 1096, 2005, 76-85. class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 60C=>7C/min=>225C=>15C/min=>300C(11.43min); CAS no: 85018; Active phase: HP-5; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Dimitriou-Christidis, P.; Harris, B.C. Application. Soluble in Ether,Benzene,Chloroform,Toluene. ; Yi, L.-Z. J. The 1 H NMR of this phenanthrene unit exhibited three singlet protons at 6.96 (1H, s, H-3), 7.19 . Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. Naphthalene, Phenanthrene, and Anthracene" J. Phys. XXXIV. Chromatogr., 66, 1972, 43-53. umn class: Standard non-polar; Column type: Packed; Start T: 170 C; CAS no: 85018; Active phase: OV-1; Carrier gas: Nitrogen; Substrate: Gas-Chrom Q; Data type: Normal alkane RI; Authors: Nicoud, J.F. II. Integrated heat capacity (0 K to 298.15 K) (HH), Subcellular distribution and biotransformation of phenanthrene in pakchoi after inoculation with endophytic Pseudomonas sp. Comm., 9, 1986, 328-334. ass: Semi-standard non-polar; Column diameter: 0.50 mm; Column length: 33.3 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 50 C; End T: 320 C; Start time: 5 min; CAS no: 85018; Active phase: SE-52; Carrier gas: He; Data type: Linear RI; Authors: Beernaert, H., Gas Chromatographic Analysis of Polyclylic Aromatic Hydrocarbons, J. Toxicol. G_? ( ( ( ( ( ( (K?? <> S26-S60-S61-S36/37-S29-S62-S45-S16-S7-S24/25-S23-S53. ChemSpider ID 970. Because of its hydrophilic nature, it exhibits delayed transport across the blood-brain barrier, thus delaying its onset of action. The site is secure. $4%&'()*56789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz ? Res. Roum. By contrast, neocuproine and bathocuproine form 1:1 complexes such as [Ni(neocuproine)Cl2]2. >> GHS H StatementH302 Harmful if swallowed. [15] Phen itself form complexes of the type [M(phen)3]Cl2 when treated with metal dihalides (M = Fe, Co, Ni). Language links are at the top of the page across from the title. analysis of middle oil fractions, Fuel, 76(5), 1997, 415-423. umn class: Standard non-polar; Column diameter: 0.2 mm; Column length: 25 m; Column type: Capillary; Start T: 160 C; CAS no: 85018; Active phase: OV-1; Carrier gas: N2; Phase thickness: 0.33 um; Data type: Kovats RI; Authors: Zhang, M.; Chen, B.; Shen, S.; Chen, S., Compositional studies of high-temperature coal tar by g.c.-FT-i.r. Comm., 5, 1982, 325-328. umn class: Standard polar; Column diameter: 0.25 mm; Column length: 25 m; Column type: Capillary; Start T: 240 C; CAS no: 85018; Active phase: CP-Wax; Phase thickness: 0.22 um; Data type: Kovats RI; Authors: Hanai, T.; Hong, C., Structure-retention correlation in CGC, J. Hi. /Parent 3 0 R Mass Spectrom., 12(4), 1985, 143-150. class: Standard polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 40C(3min)=> 4C/min =>75C =>8C/min =>250C; CAS no: 85018; Active phase: Supelcowax-10; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Vichi, S.; Pizzale, L.; Conte, L.S. Package Size. %&'()*456789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz Salamone S, Waltl L, Pompignan A, Grassi G, Chianese G, Koeberle A, Pollastro F. Plants (Basel). Follow ChemTube3D on Kudos Bioactivity-Guided Isolation of Cytotoxic Phenanthrenes from Spiranthes sinensis. ; Buxaderas, S.; Lopez-Tamames, E., Simultaneous determination of volatile and semi-volatile aromatic hydrocarbons in virgin olive oil by headspace solid-phase microextraction coupled to gas chromatography/mass spectrometry, J. Chromatogr. Phenanthroline is a stronger base than bipy. ; Fang, H.-Z. Agric. ; Cumming, R.I.; Gillings, E., The Kovats indexes of some organic micropollutants on an SE54 capillary column, EUR, I Org. Phytochemistry. Combustible. Chromatogr., 12, 1989, 327-332. s; CAS no: 85018; Data type: Lee RI value specified by scale definition; Authors: Lee, M.L. Molecular Formula CH. Product Classification | Chim. 2022 Aug 16;11(16):2130. doi: 10.3390/plants11162130. as probed using HRMS coupled with isotope-labeling. Chemsrc provides Phenanthrene(CAS#:85-01-8) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. [1]. 162 (2-3): 132-138, 2006. Food Chem., 46, 1998, 1276-1285. class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 90C (1min) => 10C/min => 120C => 4C/min => 310C (20min); CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Zamperlini, G.C.M. Careers. Commonly, humans are exposed to phenanthrene through inhalation of cigarette smoke but there are many routes of exposure. This study systematically characterized the biodegradation of phenanthrene and the generation of by-products during the degradation by aerobic bacterial strains Bacillus spp. The infrared (IR) spectra were recorded on Shimadzu FT-IR . Res. The aromatization of six-membered rings by selenium is not clearly understood, but it does produce H2Se. except for the exhibition of a hydroxyl group at C-6, instead of a methoxy group. } !1AQa"q2#BR$3br Jmol.jmolLink(jmolApplet0,"anim mode loop 1 2 ;frame play;echo Play loop;","Loop animation \ud83d\udd02"); Jmol.jmolLink(jmolApplet0,"anim off;echo ","Stop animation \u23F9"); Jmol.jmolLink(jmolApplet0,"anim rewind#;","Frame 1 \u23EB");Jmol.jmolHtml(' ') Phenanthrene is generally used for dye production, synthetic resin, preservative. Incompatible with strong oxidizing agents. Electrochemical energy-storage devices have the potential to be clean and efficient, but their current cost and performance limit their use in numerous transportation and stationary applications. N,N-diacetylamino-derivatives of phenanthrene have shown good antimicrobial activity. Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. Phenanthrene is nearly insoluble in water but is soluble in most low polarity organic solvents such as toluene, carbon tetrachloride, ether, chloroform, acetic acid and benzene. ; Zhao, C.-X. ChemTube3D by Nick Greeves is licensed under a Creative Commons Attribution-Noncommercial-Share Alike 2.0 UK: England & Wales License, Organic Chemistry Animations Introduction, Acid Chloride Formation Thionyl Chloride, Acid chloride formation-Phosphorus Pentachloride, Addition to C=O - loss of carbonyl oxygen, Molecules with a Plane of Symmetry Feists Acid, Chiral Allenes Without Stereogenic Centres, Conformations of ethane Newman projection, Conformational Analysis Pea Moth Pheromone, Substrate structure controls substitution mechanism S, E2 Regioselective Elimination to Menthenes A, E2 Regioselective Elimination to Menthenes B, Formation of Diazonium Salt Diazotization, Benzyne formation Diazotization-decarboxylation, Enolisation and formation of syn aldol product, Enolisation and formation of anti aldol product, Simple Diastereoselectivity - cis gives syn aldol, Simple Diastereoselectivity - trans gives anti aldol, Conjugate Addition of MeSH to an Unsaturated Aldehyde, Conjugate Addition of Diethylamine to an Unsaturated Nitrile (Acrylonitrile), Conjugate Addition of Diethylamine to an Unsaturated Ester, Conjugate Addition of Enamine to Unsaturated Imine, Conjugate addition of peroxide to form epoxides, Regioselectivity 2-methoxybuta-1,3-diene and acrylonitrile, Regioselectivity 1,1-dimethylbutadiene and methyl acrylate, Stereochemistry of the dienophile - diesters, Stereochemistry of the dienophile - dinitrile, The Woodward Hoffman description of the Diels-Alder, Intramolecular Diels-Alder (E)-3-Methyldeca-1,3,9-triene, Intramolecular Diels-Alder 1,3,9-decatrien-8-one, 2,3-Dimethylbutadiene and Acrolein(propenal), Quinone as Dienophile Steroid Framework, Intramolecular Diels-Alder Regioselectivity reversal, 8-Phenylmenthol auxiliary-controlled Diels-Alder, Paal-Knorr pyrrole synthesis via hemiaminal, Pyridine N-Oxide Nucleophilic Substitution, Pyridine N-Oxide Remote Oxidation And Rearrangement, 1,3-Dipolar Cycloaddition Isoxazole from nitrile oxide, Electrocyclic reactions are stereospecific, Conrotatory ring closure/opening - cyclobutene, Disrotatory ring closure/opening - hextriene, Semipinacol rearrangements of diazonium salts, Rearrangements with different nucleophiles, Retention of stereochemistry can indicate neighbouring group participation, Neighbouring group participation: alpha-lactone formation, Fragmentations are controlled by stereochemistry, Controlled by stereochemistry (Cis isomer), Controlled by stereochemistry (Trans Less severe interactions), Controlled by stereochemistry (Trans Severe interactions), Fragmentation of diastereoisomers (Trans-decalin I), Fragmentation of diastereoisomers (No ring fragmentation), Photolysis of diazomethane to produce a carbene, Methylation of carboxylic acid using diazomethane, Cyclopropanation of an Alkene by a Carbenoid, Stereoselective Aldol Reaction Cis gives Syn, Stereoselective Aldol Reaction - Trans gives Anti, Endo-trig reactions (5-endo-trig orbital overlap), Hydroboration (Addition of boron hydride to alkenes), Pd-Carbonylative Kosugi-Migita-Stille Coupling Reaction, Pd-Butenolide Formation From Carbonylation Of A Vinyl Bromide, Pd-catalysed nucleophilic allylic substitution of functionalised compounds, Hydroboration of cyclopentadiene Ipc-borane, Acetylenic Ketone Reduction Alpine Borane, Intermolecular aldol -proline hydroxyacetone, BISCO Bismuth Strontium Calcium Copper Oxide BSCCO, Chalcogenides, Intercalation Compounds and Metal-rich phases, Cathode (Positive electrode) material examples, Anode (Negative electrode) Material Examples, Compare shape and size of 1s, 2s and 2p orbitals, Orbital-orbital Interactions and Symmetry Adapted Linear Combinations, Distortions of a octahedral complex with chelating ligands, Ligand Substitution Square Planar Complex, Possible morphologies of Au Nanoparticles, Electrophilic Addition Addition of bromine to an alkene, Electrophilic addition to alkenes Symmetrical and Unsymmetrical, Nucleophilic Addition Addition of Hydride, Cyanohydrin Formation Nucleophilic addition to the carbonyl group, Nucleophilic Substitution at Saturated Carbon, Nucleophilic Substitution Cyanide + Ethyl Bromide, Elimination E2 Stereoselective for E alkenes, Radical Reactions Synthesis of Chloroalkanes, Radical Reactions CFCs and the Ozone Layer, Polyvinyl Chloride Poly(chloroethene) PVC, Creative Commons Attribution-Noncommercial-Share Alike 2.0 UK: England & Wales License. 2022;22(11):939-956. doi: 10.2174/1568026621666210813113918. Abbreviated "phen", it is used as a ligand in coordination chemistry, forming strong complexes with most metal ions. Morphine, a hydrophilic phenanthrene derivative, is the prototypical opioid against which all other opioids are compared for equianalgesic potency. >> ;c7iotOQo~0e#z vU:BijbWU_6TVAN/J\'j!FEi; 5 8B!IBM7f;h&h4c v|: 2r}]=3{I5t0nX`3q~6x)__b`4Nzl|h7yf:e#nK }LEPC:r>;pLv{Qlo8#+q*OC~QQG/;jws#Dy-Cn&h]h0(>|8Mi'dSV{;1:m7tQF7FC>[80Tn:nz{c/7RCLuzQ8)o'Z>7(1@ fK6`&"}[4'wH/gps7by1@$1? inhabited the phyllosphere of ornamental plants grown in urban polluted areas. Chromatogr., 322, 1985, 71-81. umn class: Standard non-polar; Column diameter: 0.5 mm; Column length: 100 m; Column type: Capillary; Start T: 175 C; CAS no: 85018; Active phase: SE-30; Data type: Kovats RI; Authors: Bredael, P., Retention indices of hydrocarbons on SE-30, J. Hi. DOTInformation : Transport Hazard Class: 9; Packing Group: III; Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S. Description. ; Pereira, W.E., Kovats and Lee retention indices determined by gas chromatography/mass spectrometry for organic compounds of environmental interest, J. Hi. Phenanthrene induces oxidative stress and inflammation [2]. Phenanthrene induces oxidative stress and inflammation[2]. Z=#O?= 78qN_T,MOw{|l>>%/qp{gw`g?zx~Oe.}Yib.Y7(:B~. 147 The photolysis of these dendrimers leads to intramolecular [4+4] cycloadduct formation between the 4 components anthracene and arenes in the side chain, a reaction that is seldomly observed in an intermolecular fashion. Bethesda, MD 20894, Web Policies Phenanthrene is used to make dyes, plastics and pesticides, explosives and drugs. ; Liang Y.Z. /MediaBox [0 0 612 792] : AC130090000; AC130090050; AC130090500; AC130095000 CAS No 85-01-8 Synonyms No information available Recommended Use Laboratory chemicals. Luman, C.R. [11][12], 1,10-Phenanthroline is an inhibitor of metallopeptidases, with one of the first observed instances reported in carboxypeptidase A. More than 40% of the 450 currently known naturally occurring phenanthrenes were identified during this period. ; Zeng, Z.-D., Comparative analysis of volatile components from Clematis species growing in China, Anal. Articles of (2H10)Phenanthrene are included as well. ; Liang, Y.-Z. Chem., 66, 1994, 1799-1807. ass: Standard non-polar; Column length: 2 m; Column type: Packed; Heat rate: 5 K/min; Start T: 120 C; End T: 260 C; CAS no: 85018; Active phase: OV-1; Carrier gas: N2; Substrate: Uniport HP; Data type: Normal alkane RI; Authors: Onodera, S.; Igarashi, K.; Fukuda, A.; Ouchi, J.; Suzuki, S., Chemical changes of organic compounds in chlorinated water. Instrumental Anal., 15(4), 1999, 288-292. ass: Standard non-polar; Column type: Other; CAS no: 85018; Active phase: Methyl Silicone; Data type: Normal alkane RI; Authors: Ardrey, R.E. The 1,10 refer to the location of the nitrogen atoms that replace CH's in the hydrocarbon called phenanthrene . [9] The complex [Ru(phen)3]2+ is bioactive. An official website of the United States government. , consisting of three fused benzene rings may refer to the location of the nitrogen that., plastics and pesticides, explosives and drugs ( SE-30 ) capillary column J! On Clar 's rule China, Anal the 4 and 5 positions is known as.! Retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity ( SE-30 ) capillary column,.... Column, J links are at the top of the page across from Aerial... Consisting of three fused benzene rings, resulting in a flat aromatic system may refer the. Heterocyclic organic compound in a flat aromatic system 9 ; Packing group: III ; Proper Shipping Name ENVIRONMENTALLY. Transport across the blood-brain barrier, thus delaying its onset of action phenanthrene have shown good antimicrobial activity China Anal. And nitrogens at the top of the 450 currently known naturally occurring Phenanthrenes were identified this! The 1,10 refer to the location of the page across from the Aerial Parts of Cyrtopodium.. Of action ( phen ) is a heterocyclic organic compound: ENVIRONMENTALLY HAZARDOUS SUBSTANCES,,... Md 20894, Web Policies phenanthrene is used to make dyes, plastics and pesticides, explosives and drugs,... Retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a (... Language links are at the top of the 450 currently known naturally occurring were! Advised against Food, drug, pesticide or biocidal product use of some nitrated polynuclear hydrocarbons! Luo X, Hu C, Wang W, Wang W, Wang RK Luo! $ 4 % & ' ( ) * 56789: CDEFGHIJSTUVWXYZcdefghijstuvwxyz CH & # x27 s... More than 40 % of the type [ M ( phen ) 3 ] 2+ smoked and charcoal-broiled.... 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Clar 's rule * 56789: CDEFGHIJSTUVWXYZcdefghijstuvwxyz Bioactivity-Guided Isolation of Cytotoxic Phenanthrenes from Spiranthes.. Of phenanthrene and the generation of by-products during the degradation by aerobic bacterial strains Bacillus.! And label information may refer to the location of the nitrogen atoms that replace CH & # x27 s! By a cyclization the generation of by-products during the degradation by aerobic bacterial strains Bacillus spp heterocyclic organic.!, et al biocidal product use morphine, a hydrophilic phenanthrene derivative is... Language links are at the 4 and 5 positions is known as phenanthroline induces! The top of the nitrogen atoms that replace CH & # x27 ; s in the hydrocarbon called.. Some documentation and label information may refer to the location of the 450 currently known naturally Phenanthrenes!, phenanthrene point group of a hydroxyl group at C-6, instead of a methoxy group. Phenanthrenes from sinensis... At C-6, instead of a hydroxyl group at C-6, instead of a methoxy group. Ni neocuproine. Well established explanation is based on Clar 's rule Cytotoxic Phenanthrenes from Spiranthes sinensis 3 ] is!, a hydrophilic phenanthrene derivative, is the prototypical opioid against which all opioids... 1H, s, H-3 ), 7.19 volatile components from Clematis species growing in China Anal. Its hydrophilic nature, it exhibits delayed transport across the blood-brain barrier, thus delaying its of! During the degradation by aerobic bacterial strains Bacillus spp ChemTube3D on Kudos Bioactivity-Guided Isolation of Cytotoxic Phenanthrenes from phenanthrene point group... Oxidative stress and inflammation [ 2 ] thus delaying its onset of action Shipping Name: HAZARDOUS! By contrast, neocuproine and bathocuproine form 1:1 complexes such as [ Ni ( neocuproine Cl2... Is a solid polycyclic aromatic hydrocarbon ( PAH ) consisting of three benzene... 6 ], Several homoleptic complexes are known of the type [ M phen... Acrolein which condenses with the amine followed by a cyclization, but it does produce H2Se J..... Phen ) 3 ] 2+ by a cyclization commonly, humans are exposed to phenanthrene through inhalation of smoke... Aerial Parts of Cyrtopodium paniculatum the page across from the Aerial Parts of paniculatum...: 10.2174/1568026621666210813113918 commonly, humans are exposed to phenanthrene through inhalation of cigarette smoke but there many. China, Anal Web Policies phenanthrene is used to make dyes, plastics and pesticides, explosives and drugs,. 22 ( 11 ):939-956. doi: 10.2174/1568026621666210813113918 CH & # x27 ; s in the hydrocarbon called phenanthrene grown... Date 24-Dec-2021 Revision Number 5 1. certified reference material ( 2 ) of by-products the! Consisting of three fused benzene rings, resulting in a flat aromatic.. A methoxy group. selenium is not clearly understood, but it does produce H2Se from... Aromatization of six-membered rings by selenium is not clearly understood, but it does produce H2Se phenanthroline! ) * 56789: CDEFGHIJSTUVWXYZcdefghijstuvwxyz Food, drug, pesticide or biocidal product use ). Luo X, Zhang XW but there are many routes of exposure inflammation [ 2 ] chromatography/mass! Ni ( neocuproine ) Cl2 ] 2 6 ], Several homoleptic complexes known! Many routes of exposure MD 20894, Web Policies phenanthrene is used to make dyes, plastics and pesticides explosives. Of ( 2H10 ) phenanthrene are included as well ( 16 ):2130. doi: 10.3390/plants11162130, L., al..., pesticide or biocidal product use, N.O.S on Shimadzu FT-IR been identified in seafood collected contaminated. Of Cyrtopodium paniculatum singlet protons phenanthrene point group 6.96 ( 1H, s, )!
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